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Relating the shear‐thinning curve to the molecular weight distribution in linear polymer melts

 

作者: Scott T. Milner,  

 

期刊: Journal of Rheology  (AIP Available online 1996)
卷期: Volume 40, issue 2  

页码: 303-315

 

ISSN:0148-6055

 

年代: 1996

 

DOI:10.1122/1.550742

 

出版商: The Society of Rheology

 

关键词: Shear thinning;Molecular weight distribution;Double‐reptation;Cox‐Merz rule;Constraint release;MOLECULAR WEIGHT;POLYMERS;RELAXATION TIME;SHEAR PROPERTIES;STRESS RELAXATION;VISCOSITY

 

数据来源: AIP

 

摘要:

The double‐reptation ansatz for stress relaxation in broadly polydisperse melts of linear chains relates the molecular weight distribution φ(n) and the dynamic viscosity η(ω), and has been used to infer φ(n) from rheological data. I show that the microscopic theory of constraint release implies the double‐reptation model is valid for practical distributions φ(n). I also provide a heuristic theoretical argument for the Cox–Merz empirical rule that the shapes of the functions η*(ω) and η(γ̇) are similar, which allows the shear‐thinning curve to be predicted.

 

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