Yielding behavior of glassy polymers. III. Relative influences of free volume and kinetic energy
作者:
K.C. Rusch,
R.H. Beck,
期刊:
Journal of Macromolecular Science, Part B
(Taylor Available online 1970)
卷期:
Volume 4,
issue 3
页码: 621-633
ISSN:0022-2348
年代: 1970
DOI:10.1080/00222347008229378
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The free-volume model for interpreting the initial yielding behavior of glassy polymers is extended to include kinetic energy influences. Molecular mobility is assumed to be determined by the product of the probabilities of attaining sufficient local free volume to allow molecular rearrangement, and kinetic energy to overcome restraining forces. Yielding then is initiated at the point where the free-volume increase resulting from the dilational component of the applied stress is sufficient to bring the local molecular mobility to that characteristic of the unstressed polymer at Tg.
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