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An Approximate Kinetic Treatment of Slow‐Initiated Living Polymerization. I. First‐Order Initiation and Propagation

 

作者: Elena Ceausescu,   R. Bordeianu,   Anca Ion,   E. Buzdugan,   Rodica Stancu,   Irina Cerchez,   P. Ghioca,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1989）
卷期: Volume 26, issue 11  

页码: 1539-1553

 

ISSN:0022-233X

 

年代: 1989

 

DOI:10.1080/00222338908052070

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A new method for deriving the initiation rate constant for a slowinitiated living polymerization process in which all reactions are first order with respect to all participants is presented. The method is based upon an approximate analytical solution of the set of differential equations modeling this class of processes. The solution is found by asymptotic expansion of the unknown functions, using a dimensionless parameter which characterizes the process.

 

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