High-Pressure Fluid Injection in Supersonic Beam Mass Spectrometry With Resonant Two-Photon Ionization
作者:
Chung Hang Sin,
Ho-Ming Pang,
David M. Lubman,
期刊:
Instrumentation Science & Technology
(Taylor Available online 1988)
卷期:
Volume 17,
issue 1-2
页码: 87-111
ISSN:1073-9149
年代: 1988
DOI:10.1080/10739148808543668
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A novel apparatus was designed for the introduction of supersonic jets of supercritical CO2, N2O and high-pressure hot liquids such as methanol and water. The key features of this experiment are a pulsed injection source, which was designed with efficient liquid nitrogen cryopumping to operate at pressures of up to 380 atm and nearly 200°C. The reduction in duty cycle provided by a pulsed source has allowed the use of a 200 μm orifice, which significantly increases the on-axis density in the jet compared to continuous expansions where a 10 μm orifice is customarily used. Resonant two-photon ionization is then used to softly ionize the molecules in the beam for mass analysis and detection in a time-of-flight mass spectrometer.
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