Effects of Lateral Substituents on Mesomorphic Behavior. II. 4-(4-Alkoxybenzylideneamino)phenyl Benzoates
作者:
Y. Matsunaga,
T. Mukougawa,
Y. Saito,
期刊:
Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals
(Taylor Available online 1998)
卷期:
Volume 317,
issue 1
页码: 237-243
ISSN:1058-725X
年代: 1998
DOI:10.1080/10587259808047118
出版商: Taylor & Francis Group
关键词: Nematic;smectic;lateral substituent
数据来源: Taylor
摘要:
The mesomorphic properties of 4-(4 alkoxybenzylideneamino)phenyl 2- and 3-X-benzoates, whereX= Me or Cl, were examined. While the nematic-isotropic transition temperatures of the 2-Me and 2-Cl derivatives are nearly identical, the 3-Cl derivatives give higher transition temperatures than the 3-Me derivatives, the difference being 20°C or more. The nematic phase given by the lower homologous members of the 2-Me derivative is thermally more stable than that of the 3-Me derivative but this relation is reversed for the higher members. In contrast to the purely nematogenic parent compounds, the 3-halogeno derivatives of the higher homologous members exhibit a smectic A phase.
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