Surface Properties of Styrene-Tetrahydrofuran Block Copolymers
作者:
Yuya Yamashita,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1979)
卷期:
Volume 13,
issue 3
页码: 401-413
ISSN:0022-233X
年代: 1979
DOI:10.1080/00222337908068109
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Surface properties of styrene-tetrahydrofuran (St-THF) block copolymers (AB and ABA type) were studied. Morphology observed by electron micrography showed the formation of fibrils of poly-THF covered with poly-St for THF-rich block copolymers and the accumulation of poly-THF segments for St-rich block copolymers. The poly-THF segment was found to have a surface of activity 3 dyne/cm lower than the poly-St segment. Modification of the poly-St surface by adding St-THF block copolymers was examined by measuring the surface tension drop during heating. Inverse gas chromatography of the block copolymers revealed that the surface of St-rich block copolymer changes from poly-St to poly-THF on baking. The contact angle of water droplets was a linear function of surface composition, and water wettability of St-rich block copolymers by accumulation of surface active poly-THF segment was indicated.
点击下载:
PDF (515KB)
返 回