Viscosity of Aluminium Chloride and Acidic Sodium Chloroaluminate Melts
作者:
W. Brockner,
K. Tørklep,
H. A. Øye,
期刊:
Berichte der Bunsengesellschaft für physikalische Chemie
(WILEY Available online 1979)
卷期:
Volume 83,
issue 1
页码: 1-11
ISSN:0005-9021
年代: 1979
DOI:10.1002/bbpc.19790830102
出版商: Wiley‐VCH Verlag GmbH&Co. KGaA
数据来源: WILEY
摘要:
AbstractThe viscosity of NaCl‐AlCl3melt mixtures has been determined in the range 0.50 ≤X AlCl 3≤ 0.80, 160°C to 300°C. The viscosity of pure AlCl3was measured over the temperature span 196°C to 286°C. A recently designed oscillating vessel viscometer was used. The method, which utilizes closed cylindrical cups subjected to vapour pressures exceeding 11 atm, is absolute and requires no calibration against reference liquids. Results are corrected for surface effects and for evaporation within the crucible. Applying Arrhenius temperature dependencies and the Arrhenius mixing rule, the viscosity is expressed as a function of temperature and composition with an overall standard deviation of 0.4% when the presence of AlCl−4, Al2Cl−7, Al3Cl−10, a
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