A study of molecular re-orientation in liquid acetonitrile by nuclear spin-lattice relaxation
作者:
D.E. Woessner,
B.S. Snowden,
E. Thomas Strom,
期刊:
Molecular Physics
(Taylor Available online 1968)
卷期:
Volume 14,
issue 3
页码: 265-273
ISSN:0026-8976
年代: 1968
DOI:10.1080/00268976800100291
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Studies of the nitrogen, deuteron and proton relaxation rates of liquid acetonitrile at various temperatures were carried out by pulsed N.M.R. techniques. Re-orientation of the methyl group about its symmetry axis is found to be approximately ten times faster than the re-orientation of the nitrile group. Analysis of the data provides an example of a large room-temperature contribution to the intramolecular relaxation component by a spin-rotation interaction. Previously sizeable spin-rotation interactions were considered to be insignificant for organic molecules at room temperature.
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