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ChemInform Abstract: Doubly Destabilized Carbocations. Strong Aryl Delocalization and the Attenuation of Rate Decelerating Effects of CF3and CN Groups.

 

作者: A. D. ALLEN,   V. M. KANAGASABAPATHY,   T. T. TIDWELL,  

 

期刊: Chemischer Informationsdienst  （WILEY Available online 2016）
卷期: Volume 17, issue 41  

页码: -

 

ISSN:0009-2975

 

年代: 2016

 

DOI:10.1002/chin.198641101

 

出版商: WILEY‐VCH Verlag GmbH

 

数据来源: WILEY

 

摘要:

AbstractKinetic results of solvolysis in (II) and different other solvents are interpreted in terms of carbocationic transition states and intermediates in which the Charge is largely delocalized onto the aryl group.

 

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