Reaction of four-membered silicocarbon heterocycles with nucleophilic reagents
作者:
N.S.Nametkin,
E.D.Babich,
V.N.Karel'skii,
V.M.Vdovin,
期刊:
Bulletin of the Academy of Sciences of the USSR, Division of chemical science
(Springer Available online 2004)
卷期:
Volume 20,
issue 5
页码: 948-953
ISSN:0568-5230
年代: 2004
DOI:10.1007/BF00862201
出版商: Springer_US-Boston
数据来源: Springer
摘要:
1.A study was made of the opening of the heterocycle in the series of mono- and disilacyclobutanes under the influence of alcohols and alcoholic alkali. The heterocycles with one silicon atom possess a much greater reactivity.2.Substitutents on the silicon atom, which have a positive inductive effect, increase the stability of the silicocarbon bonds of the ring, while substituents with a negative inductive effect decrease the stability.
点击下载:
PDF
(500KB)
返 回