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Reaction of four-membered silicocarbon heterocycles with nucleophilic reagents

 

作者: N.S.Nametkin,   E.D.Babich,   V.N.Karel'skii,   V.M.Vdovin,  

 

期刊: Bulletin of the Academy of Sciences of the USSR, Division of chemical science  (Springer Available online 2004)
卷期: Volume 20, issue 5  

页码: 948-953

 

ISSN:0568-5230

 

年代: 2004

 

DOI:10.1007/BF00862201

 

出版商: Springer_US-Boston

 

数据来源: Springer

 

摘要:

1.A study was made of the opening of the heterocycle in the series of mono- and disilacyclobutanes under the influence of alcohols and alcoholic alkali. The heterocycles with one silicon atom possess a much greater reactivity.2.Substitutents on the silicon atom, which have a positive inductive effect, increase the stability of the silicocarbon bonds of the ring, while substituents with a negative inductive effect decrease the stability.

 

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