Catalytic Decomposition of Dibenzyl Disulfide and Dibenzyl Sulfide on Iron Powder
作者:
C.H. Bovington,
B. Dacre,
期刊:
A S L E Transactions
(Taylor Available online 1982)
卷期:
Volume 25,
issue 1
页码: 44-48
ISSN:0569-8197
年代: 1982
DOI:10.1080/05698198208983063
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
The liquid phase adsorption and decomposition of dibenzyl disulfide and dibenzyl monosulfide on iron powder from hexadecane has been studied as a function of time from 130°C-170°C. Products of decomposition have been identified. The rate of decomposition is pseudo first order for each compound for more than 50 percent decomposition. Activation energies have been calculated from the temperature dependence of the pseudo first order rate constants. Some of our results differ from those of previous workers.
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