Nitrenium ions in N‐chloro‐α‐amino acids decomposition?
作者:
X. L. Armesto,
M. Canle L.,
M. Losada,
J. A. Santaballa,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1993)
卷期:
Volume 25,
issue 1
页码: 1-8
ISSN:0538-8066
年代: 1993
DOI:10.1002/kin.550250102
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThis article deals with the kinetics of decomposition of four isomers: NCl‐(L)‐2‐Aminohexanoic acid, NCl‐(L)‐Leucine, NCl‐(L)‐Isoleucine, and NCl‐(L)‐tert‐Leucine, in mild acid and basic aqueous solution. An alternative mechanism for this process which takes place through a nitrenium‐like ion transition state is proposed. This mechanism is in consonance with the experimental data and with those available from the literature
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