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Conducting Properties of Assembled Metal Complexes

 

作者: Reizo Kato,   Eiji Watanabe,   Masahiro Fujiwara,   Yoshiaki Kashimura,   Yoshinori Okano,   Jun-Ichi Yamaura,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 2000）
卷期: Volume 343, issue 1  

页码: 1-8

 

ISSN:1058-725X

 

年代: 2000

 

DOI:10.1080/10587250008023495

 

出版商: Taylor & Francis Group

 

关键词: molecular conductor;metal dithiolene complex;resistivity;crystal structure;pressure effect;band calculation

 

数据来源: Taylor

 

摘要:

Assembled metal complexes, where organic π electrons and metal d electrons coexist, form one important class of materials in the field of molecular “metals” and “superconductors”. Among them, molecular conductors based on metal-dithiolene complexes are known to exhibit various conducting properties. Recent studies on molecular conductors based on the acceptor-type Pd(dmit)2[dmit=2-thioxo-1,3-dithiol-4,5-dithiolate] and the donor-type Ni(edo)2[edo = ethylenedioxydithiolate] and related materials are described.

 

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