首页   按分类浏览 期刊浏览 卷期浏览 Utility of branched chain carboxylic acids in the manufacture of driers
Utility of branched chain carboxylic acids in the manufacture of driers

 

作者: AlfredFischer,  

 

期刊: Journal of the American Oil Chemists’ Society  (Springer Available online 2007)
卷期: Volume 43, issue 7  

页码: 469-471

 

ISSN:0003-021X

 

年代: 2007

 

DOI:10.1007/BF02682418

 

出版商: Springer-Verlag-Berlin-Heidelberg

 

数据来源: Springer

 

摘要:

To be useful in the manufacture of driers, a carboxylic acid must yield lead, cobalt, manganese, calcium and zinc soaps which are soluble in paint vehicles and petroleum hydrocarbon thinners. The drying metal soaps of a number of saturated branched chain carboxylic acids were prepared to determine the relationship of acid structure to metal soap solubility. It was found that with the exception of 4-ethyl-5,5-dimethyl-hexanoic acid those branched chain acids containing at least six carbon atoms in the longest straight chain yielded soluble drying metal soaps and were therefore useful in drier manufacture. soluble “basic” lead soaps, pale-colored manganese soaps and reddish purple cobalt soaps were obtained from acids lacking in alpha branching. Alpha-branched acids yielded insoluble basic lead soaps, dark manganese soaps and dark blueviolet cobalt so

 

点击下载:  PDF (320KB)



返 回