Star-Shaped Alkyl Carbamates as Pour Point Depressants
作者:
Johannes Smid,
Xin Chen,
Chen-Lin Xia,
期刊:
Tribology Transactions
(Taylor Available online 1997)
卷期:
Volume 40,
issue 2
页码: 279-282
ISSN:1040-2004
年代: 1997
DOI:10.1080/10402009708983656
出版商: Taylor & Francis Group
关键词: Pour Point Depressant Additives;Pour Point;Hydrocarbons
数据来源: Taylor
摘要:
A series of trialkyl carbamates of the general formula HC(Ph NHCOOCnH2n+1)3with n = 16, 18, 20 and 22 were synthesized from alkanols and tris(p-isocyanatophenyl)methane. The star-shaped compounds effectively depress the pour point of wax-containing paraffin oil. A quantity of 0.1 wt.% of the C18 derivative, by far the most effective depressant, reduces the pour point of paraffin oil containing 11.5 wt.% wax (mp 56–61° C) from 33° C to - 4°C. The extent of the depression varies with the concentration and composition of the wax. The depressants are ineffective when pure alkane waxes are added to the paraffin oil.
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