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Limiting electrical response of conductive and dielectric systems, stretched-exponential behavior, and discrimination between fitting models

 

作者: J. Ross Macdonald,  

 

期刊: Journal of Applied Physics  (AIP Available online 1997)
卷期: Volume 82, issue 8  

页码: 3962-3971

 

ISSN:0021-8979

 

年代: 1997

 

DOI:10.1063/1.365704

 

出版商: AIP

 

数据来源: AIP

 

摘要:

Given a fitting model, such as the Kohlrausch–Williams–Watts (KWW)/stretched-exponential response, three plausible approaches to fitting small-signal frequency or time-response data are described and compared. Fitting can be carried out with either of two conductive-system formalisms or with a dielectric-system one. Methods are discussed and illustrated for deciding which of the three approaches is most pertinent for a given data set. Limiting low- and high-frequency log–log slopes for each of the four immittance levels are presented for several common models; cutoff effects are considered; and an anomaly in the approach to a single-relaxation-time Debye response for one of the conductive-system approaches is identified and explained. It is found that the temporal response function for the most appropriate conductive-system dispersion (CSD) approach, designated the CSD1, one long used in approximate form for frequency-response data analysis, does not lead to stretched-exponential transient behavior when a KWW response model is considered. Frequency-domain fitting methods and approaches are illustrated and discriminated using 321 and 380 KNa2O–3SiO2data sets. The CSD1 approach using a KWW model is found to be most appropriate for fitting these data exceedingly closely with a complex nonlinear least-squares procedure available in the free computer programLEVM.Detailed examination and simulation of the approximate, long-used CSD1 modulus fitting formalism shows the unfortunate results of its failure to include separately the effects of the always present high-frequency-limiting dielectric constant,&egr;D∞.The stretched-exponential exponent, &bgr;, associated with this fitting approach has always been misidentified in the past, and even after its reinterpretation, the result is likely to be sufficiently approximate that most physical conclusions derived from such fitting will need reevaluation. ©1997 American Institute of Physics.

 

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