Extraction of microquantities of Sc, Mn(II), Ni, Co, Cu, Zn, Ga, Y, Pd, Cd, In, La, Eu, Tl(III). Pb, Bi, Th, and U(VI) from aqueous solutions of HNO3by solutions of phosphoryl-containing podands in dichloroethane has been studied. The influence of the podand molecule structure on the process of extraction is considered. The stoichiometry of the complexes extracted into the organic phase has been established.