The present work cites the investigation results of19F NMR spectra in polyerystalline compounds of the Men[PtF6]mtype, where Me - Li+, Na+, K+, Ca2+, Sr2+, Ba2+, La3+and Ag+. The use of a NMR spectrometer with high field stress (∼24 kOe) made possible the observation of different chemical shifts in solids of NMR signals from two nonequivalent fluorine types in octahedric complexes of [PtF6]2-.19NMR and Structure of Pt (IV) Hexafluorocomplexes