The structure and magnetic properties of μ3‐oxotriiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2
作者:
De‐Gang Fu,
Guo‐Xiong Wang,
Wen‐Xia Tang,
Kai‐Bei Yu,
期刊:
Chinese Journal of Chemistry
(WILEY Available online 1994)
卷期:
Volume 12,
issue 1
页码: 43-51
ISSN:1001-604X
年代: 1994
DOI:10.1002/cjoc.19940120106
出版商: Wiley‐VCH Verlag GmbH&Co. KGaA
关键词: Crystal structure;magnetic exchange;triirou complex
数据来源: WILEY
摘要:
AbstractA new μ3‐O triiron(III) complex [Fe3O(OBz)6(CH3OH)3](NO3)(CH3OH)2(HOBZ = benzoic acid) has been synthesized, its structure has been determined and variable temperature magnetic susceptility has also been measured. In the molecule, three iron atoms formed an equilateral triangle with μ3‐O in center. The fitting to the magnetic susceptibility showed that an intramolecular antiferromagnetic exchange interaction occurred between iron atoms withJ=‐25.51 cm−1, and a weaker intermolecular autiferromagnetic exchange interaction occurred withzJ'=
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