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Metal-Free Functionalization of the Unactivated Carbon-Hydrogen Bond: the Oxidation of Cycloalkanes to Cycloalkanones with Ozone

 

作者: Barbara Barletta,   Ezio Bolzacchini,   Luciano Fossati,   Simone Meinardi,   Marco Orlandi,   Bruno Rindone,  

 

期刊: Ozone: Science & Engineering  （Taylor Available online 1998）
卷期: Volume 20, issue 2  

页码: 91-98

 

ISSN:0191-9512

 

年代: 1998

 

DOI:10.1080/01919519808547278

 

出版商: Taylor & Francis Group

 

关键词: Ozone;Cyclodecane;Cyclodecanone;Cyclodecanol;Cyclohexane;10-Oxodecanoic acid;Decandioic Acid;Cyclohexanone;Cyclohexanol

 

数据来源: Taylor

 

摘要:

Cyclodecane and cyclohexane were converted to the corresponding cycloalkanones and cycloalkanols upon ozonation at acidic pH. Also some ring cleavage to dicarboxylic acids or aldehydoacids was observed.

 

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