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A Mirror Effect in the Intensities of the Secondary Transitions of Benzyl Acetate and Phenethyl Propionate

 

作者: Bernard Vidal,   Annick Darry-henaut,  

 

期刊: Spectroscopy Letters  （Taylor Available online 1987）
卷期: Volume 20, issue 9  

页码: 749-755

 

ISSN:0038-7010

 

年代: 1987

 

DOI:10.1080/00387018708081582

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The intensity of the secondary transition (towards 260 nm)of the benzene chromophore in toluene derivatives, has been linked to distorsions of the D6hsymmetry which are induced by the electronic effects of the substituent. These distorsions arise through the CαH2σπhyperconjugative coupling, involving and the substituent on Cα

 

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