Spectrophotometric Study on the Uranium Complexes with 4-(2-Thiazolylazo) Resorcinol in the Presence of Zephiramine
作者:
T. Ozaki,
期刊:
Analytical Letters
(Taylor Available online 1982)
卷期:
Volume 15,
issue 7
页码: 581-593
ISSN:0003-2719
年代: 1982
DOI:10.1080/00032718208064403
出版商: Taylor & Francis Group
关键词: 4-(2-thiazolylazo) resorcinol;uranium;zephiramine;phosphate buffer
数据来源: Taylor
摘要:
The effect of tetradecyl-dimethyl-benzyl-ammonium chloride (zephiramine=Z+Cl-) on uranium with 4-(2-thiazolylazo) resorcinol (TAR) was studied. In the presence of zephiramine, a uranium-TAR complex was stabilized and solublized in aqueous media at a pH around 7. The addition of zephiramine made it possible to use phosphate buffers which have large buffer capacity in the optimum range for the determination of uranium. Almost all interfering ions can be masked with an EDTA solution. As a result, a sensitive and simple method for the determination of uranium was developed.
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