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Formation and Stability of the Helical Tubuland Diol Inclusion Lattice

 

作者: Roger Bishop,   DonaldC. Craig,   IanG. Dance,   MarciaL. Scudder,   AlisonT. Ung,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  （Taylor Available online 1992）
卷期: Volume 211, issue 1  

页码: 141-146

 

ISSN:1058-725X

 

年代: 1992

 

DOI:10.1080/10587259208025813

 

出版商: Taylor & Francis Group

 

关键词: inclusion compounds;crystal structures;host-guest chemistry;helical tubul and hosts;helical tubulate compounds;hydrogen bonding

 

数据来源: Taylor

 

摘要:

Alicyclic oil 's of specific design crystallise with a lattice enclosing a series of parallel helical canals which trap a wide range of guest molecules. Typical structures of these helical tubulate compounds are presented. The canal sizes and geometries vary considerably depending on the actual diol utilised. Lattices with smaller canals retain the helical tubuland structure in the absence of guests, whereas those with larger canals collapse to a close-packed structure.

 

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