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Molecular Orientation of Perylene-Like Dyes in Liquid Crystal 80CB

 

作者: Danuta Bauman,   Ewa Mykowska,   Eryk Wolarz,  

 

期刊: Molecular Crystals and Liquid Crystals Science and Technology. Section A. Molecular Crystals and Liquid Crystals  (Taylor Available online 1998)
卷期: Volume 321, issue 1  

页码: 333-347

 

ISSN:1058-725X

 

年代: 1998

 

DOI:10.1080/10587259808025100

 

出版商: Taylor & Francis Group

 

关键词: liquid crystal;dichroic dye;absorption;fluorescence;order parameter

 

数据来源: Taylor

 

摘要:

The polarized absorption and fluorescence spectra of some dichroic fluorescent dyes (derivatives of 3,4,9-perylenetricarboxylic acid and 3,4,9,10-perylenetetracarboxylic acid) oriented in liquid crystal 80CB have been recorded as a function of temperature. On the basis of these spectra the order parameters <P2> and <P4> and orientational distribution function have been determined. The conclusions about the influence of the molecular structure of the dyes on their orienting properties in uniaxial liquid crystalline phases have been drawn.

 

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