Optical properties of group-V atom-vacancy pairs in silicon
作者:
G.D. Watkins,
期刊:
Radiation Effects and Defects in Solids
(Taylor Available online 1989)
卷期:
Volume 111-112,
issue 1-2
页码: 487-500
ISSN:1042-0150
年代: 1989
DOI:10.1080/10420158908213023
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Two optical absorption bands are identified as arising from the negative charge state of each of the P-, As-, and Sb-vacancy pairs in silicon. The more prominent band for each is at 6150, 6000, and 5500 cm−1, respectively. A second broader partially overlapping band at ∼8500 cm−1is also present for each. Dichroism produced in the bands by uniaxial stress reveals a static Jahn-Teller distortion of opposite sign to that for the neutral state previously studied by EPR. The absorption bands can be identified as electron transitions from filled to empty orbitals of a simple one-electron molecular orbital model for the defect.
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