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On the Time‐Temperature Superposition Principle of Dilute Polymer Liquids

 

作者: N. Phan‐Thien,  

 

期刊: Journal of Rheology  (AIP Available online 1979)
卷期: Volume 23, issue 4  

页码: 451-456

 

ISSN:0148-6055

 

年代: 1979

 

DOI:10.1122/1.549528

 

出版商: The Society of Rheology

 

数据来源: AIP

 

摘要:

In this work, a simple bead‐spring (dumbbell) model is employed together with the Langevin analysis to show that the master curves for stress must be made in terms of the groupS/ρT,andSis the stress tensor,Tthe absolute temperature, and ρ the density of the solvent. The time‐temperature shift factor is shown to beηs(T0)T/ηs(T)T0,whereηs(T)is the solvent viscosity at temperatureT.

 

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