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Syntheses of Model Oligosaccharides of Biological Significance. VI. Glycosylation at C-3 of Galactose: A Synthesis of Trideuterio-Methyl 3-O-(-Acetamido-2-Deoxy-β-D-Glucopyranosyl)-β-D-Galactopyranoside

 

作者: DennisM. Whitfield,   JeremyP. Carver,   JiriJ. Krepinsky,  

 

期刊: Journal of Carbohydrate Chemistry  (Taylor Available online 1985)
卷期: Volume 4, issue 3  

页码: 369-379

 

ISSN:0732-8303

 

年代: 1985

 

DOI:10.1080/07328308508070187

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The title disaccharide was prepared by glycosylation of either methyl trideuteriomethyl 2-O-benzoyl-4,6-benzylidene-β-D-galactopyranoside or trideuteriomethyl-4,6-O-benzylidene-β-D-galactopyranoside with 3,4,6-tri-Oi-acetyl 2-deoxy-2-phthalimido-β-D-glucopyranosyl bromide using silver zeolite 13X or silver triflate as promoters.

 

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