Very Small Metallic and Bimetallic Clusters: The Metal Cluster-Metal Surface Analogy in Catalysis and Chemisorption Processes
作者:
GeoffreyA. Ozin,
期刊:
Catalysis Reviews
(Taylor Available online 1977)
卷期:
Volume 16,
issue 1
页码: 191-289
ISSN:0161-4940
年代: 1977
DOI:10.1080/03602457708079637
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Why very small metal clusters? From a practical standpoint, industry often wants its metallic catalysts in a finely divided form so as to maximize the surface area available for a given mass of metal. Obviously, stability toward agglomeration and reactant accessibility are also necessary prerequisites for the successful performance of highly dispersed metal particle catalysts. Solid supported catalysts usually achieve this end. Moreover, such catalysts offer the advantage of convenient handling in a process system; however, technical metallic catalysts are usually ill defined and poorly understood, and better defined systems are necessary for fundamental experimental work.
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