SOLVENT EXTRACTION EQUILIBRIUM OF NICKEL FROM AMMONIACAL SOLUTIONS BY LIX 64N
作者:
Carmen Pazos,
Juan PabloS. Curieses,
José Coca,
期刊:
Solvent Extraction and Ion Exchange
(Taylor Available online 1991)
卷期:
Volume 9,
issue 4
页码: 569-591
ISSN:0736-6299
年代: 1991
DOI:10.1080/07366299108918071
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Equilibrium data for the solvent extraction of nickel from amraoniacal solutions by LIX 64N (10 vol%) dissolved in kerosene (15% aromatic content) are reported. The effect of NH3/aq) concentration, LIX 64N concentration, pH and temperature are shown. The stoichiometry of the Ni-active oxime in LIX 64N complex was ascertained by spectrophotometry studies. A mathematical mechanistic model was developed for the prediction of extraction distribution coefficients as a function of pH. The model predicts more accurate results at high pH values, as could be expected taking into consideration the assumptions made in developing the model.
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