Computer simulation of the mechanical alpha relaxation in isothermally crystallized high‐density polyethylene
作者:
J. A. González‐Orozco,
期刊:
Journal of Polymer Science Part B: Polymer Physics
(WILEY Available online 1993)
卷期:
Volume 31,
issue 1
页码: 47-59
ISSN:0887-6266
年代: 1993
DOI:10.1002/polb.1993.090310107
出版商: John Wiley&Sons, Inc.
关键词: dynamic mechanical behavior of HDPE, computer model for alpha relaxation in;polyethylene, high density, computer model for alpha relaxation in
数据来源: WILEY
摘要:
AbstractThe influence of thermal history on the dynamic mechanical behavior in the alpha relaxation region of high‐density polyethylene (HDPE) is predicted using computer modeling. The model considers the mechanical alpha relaxation as a succession of cooperative single movements occurring within the defect region of the crystal lattice that finally produce a relative displacement between lamellae. A distribution function of the number of such single steps is postulated considering topological properties of the sample: branch content and molecular weight. To carry out the simulation, the model uses the spectrum of the sample subjected to fast cooling as a reference system. In addition, the crystallinity and the segregated material content for the particular thermal history of the object of study are also required. Loss modulus spectra are generated using balance of energy considerations, and a few examples are presented together with several experimental results. © 1993 John Wiley&Sons, I
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