Vinyl Polymerization Initiated by Reducing Compounds of Transition Metals. XI. Two-step Selective Graft Copolymerization
作者:
N. Moszner,
M. Hartmann,
J. Opfermann,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1986)
卷期:
Volume 23,
issue 10
页码: 1165-1177
ISSN:0022-233X
年代: 1986
DOI:10.1080/00222338608069486
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Grafting of methyl methacrylate onto poly(methyl-4-vinylbenzyl-sulfoxide-co-trichloroethyl methacrylate) is initiated by molybdenum (III) chloride in ethylene chloride. In a second step the obtained graft copolymers are grafted with styrene in the presence of chromium(II) acetate and morpholinocyclohexene in dimethylformamide. By this stepwise selective graft copolymerization technique, polymers can be tailored to give the required properties.
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