van der Waals interactions between a molecule and a small metallic sphere
作者:
B. Labani,
C. Girard,
S. Maghezzi,
期刊:
Molecular Physics
(Taylor Available online 1990)
卷期:
Volume 69,
issue 1
页码: 85-95
ISSN:0026-8976
年代: 1990
DOI:10.1080/00268979000100061
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
A calculation of the van der Waals contribution to the physisorption energy is performed for molecules interacting with small metallic spheres. The induction contribution is introduced by using the first field gradient susceptibilities of the sphere at zero frequency. In order to illustrate the non local effects as well as the importance of the curvature of the metal particle on the magnitude of the physisorption energy, we present numerical results for typical systems (HF, HCl on Ag, Cu and Al).
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