AbstractSeveral Fe–Al and Fe–Al–Zn alloys were vacuum melted, annealed at 450°C under atmospheric pressure, and then quenched in iced water. The structure and composition of phases were determined using microstructural, X-ray diffraction, and X-ray energy dispersive analyses. The maximum solubility of zinc was found to be 5·3 wt-% in FeAl3, 20·9 wt-% in Fe2Al5, and 2·0 wt-% in FeAl at 450°C. Based on these results, an isothermal section for the aluminium rich corner of the Fe–Al–Zn ternary phase diagram is proposed.MST/1196