The Effect of Diffusion Coefficient Error on the Value of n in Common Equations of Electroanalytical Chemistry
作者:
NewtonC. Fawcett,
RoyD. Caton,
期刊:
Analytical Letters
(Taylor Available online 1981)
卷期:
Volume 14,
issue 3
页码: 175-180
ISSN:0003-2719
年代: 1981
DOI:10.1080/00032718108081393
出版商: Taylor & Francis Group
关键词: diffusion coefficients;error analysis;electroanalytical equations
数据来源: Taylor
摘要:
Error expressions derived from the commonly used equations of electroanalytical chemistry using Taylor's series show how a calculated value of n, the number of electrons transferred, depends on the error in D, the diffusion coefficient. The error relationships for chronoamperometry, polarography, chronopotentiometry, and voltammetry at stationary and rotated-disk electrodes are given. It is found that when the relative error in D is less than 10% a simple linear relationship between the error in D and n is a satisfactory approximation.
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