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Recent Progress in the Preparation of Functional Methacrylate Polymers

 

作者: F.P. Boettcher,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  (Taylor Available online 1985)
卷期: Volume 22, issue 5-7  

页码: 665-678

 

ISSN:0022-233X

 

年代: 1985

 

DOI:10.1080/00222338508056629

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Application of anionic polymerization and group transfer polymerization to the synthesis of methacrylate polymers with one or two functional endgroups and with functional groups in the side chain is described. Success in the preparation of end-functional polymers depends largely on the absence of chain transfer and chain termination reactions. The higher stability of living chains in group transfer polymerization at temperatures as high as 100°C makes it the preferred route to functional polymers.

 

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