Crystallization of polymers under high tension: A dendrite model
作者:
William A. Tiller,
J. M. Schultz,
期刊:
Journal of Polymer Science: Polymer Physics Edition
(WILEY Available online 1984)
卷期:
Volume 22,
issue 2
页码: 143-161
ISSN:0098-1273
年代: 1984
DOI:10.1002/pol.1984.180220201
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractThe crystallization of highly oriented homopolymer melts (or glasses) is modeled. It is shown that in such cases heat flow controls the kinetics and microstructure of the transforming material. The situation is modeled similarly to the growth of a thermal dendrite, with the inclusion of large and variable concentrations of defects in the fibrillar crystals. Expressions relating the undercooling, growth velocity, filament tip radius, and defect concentration to a normalized tensile force are derived. Example predictions for the case of isotactic polystyrene are given.
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