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Structural Aspects of Polymerization in Crystalline Ionic Monomers: Comparison of Barium Methacrylate Monohydrate and Anhydrate

 

作者: M.J. Bowden,   C.H. L. Kennard,   J.H. O'donnell,   R.D. Sothman,   N.W. Isaacs,   G. Smith,  

 

期刊: Journal of Macromolecular Science: Part A - Chemistry  （Taylor Available online 1978）
卷期: Volume 12, issue 1  

页码: 63-72

 

ISSN:0022-233X

 

年代: 1978

 

DOI:10.1080/00222337808081022

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

Barium methacrylate monohydrate, Ba2+[CH2˭C(CH3)COO−]2·H2O, may be readily polymerized in the crystalline state by γ-irradiation. However, except under special conditions, there is negligible polymer produced when anhydrous barium methacrylate is exposed to γ-irradiation. The differences in polymer iz-ability are considered in relation to the detailed spatial arrangements of the methacrylate molecules and molecular mobility assimiated with development of disorder.

 

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