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SOLUBILIZATION OF OIL IN DISCONTINUOUS CUBIC LIQUID CRYSTAL IN POLY(OXYETHYLENE)nOLEYL ETHER SYSTEMS

 

作者: Kazuki SHIGETA,   Carlos RODRIGUEZ,   Hironobu KUNIEDA,  

 

期刊: Journal of Dispersion Science and Technology  (Taylor Available online 2000)
卷期: Volume 21, issue 7  

页码: 1023-1042

 

ISSN:0193-2691

 

年代: 2000

 

DOI:10.1080/01932690008913328

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The structural change of the discontinuous cubic (I1) phase upon addition of oil (heptane, decane, and hexadecane) is investigated by small-angle x-ray scattering. In polyoxyethylene oleyl ether (C18.1EOn) systems having long polyoxyethylene chain (n=19.2, 30.1, and 50.8), theI1phase is formed in a wide concentration range. Only in C18.1EOnEO19.2EOnsystems, the structure of the I1phase changes from body-centered to face centered cubic lattice upon addition of oil. According to the analysis of the change in effective cross-sectional area, the solubilization of hexadecane increases the repulsion between polyoxyethylene chains, while solubilization of heptane makes it decrease. The solubilization of decane keeps the repulsion constant. Since the repulsion hampers the curvature change due to the solubilization, the solubilization capacity is in the order, heptane>decane>hexadecane. The oil penetration and nonpenetration into the palisade layer are also discussed in term of the change in the effective volume of the lipophilic part in the surfactant molecule.

 

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