We have performed high resolution extreme ultraviolet (EUV) photon and Auger electron measurements to elucidate single and double capture processes in Ne8++He single collisions at 80 keV impact energy. Numerous new transitions both in the Auger and the EUV spectra have been identified by means of extensive theoretical calculations and correlation diagrams. These data are of importance for the modeling of impurities in plasma and for future plasma diagnostics. ©1997 American Institute of Physics.