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Solution Solvent Couples Solute Molecules and Enhances Their Internal Tension

 

作者: H.T. Hammel,  

 

期刊: Physics and Chemistry of Liquids  (Taylor Available online 1984)
卷期: Volume 13, issue 4  

页码: 255-267

 

ISSN:0031-9104

 

年代: 1984

 

DOI:10.1080/00319108408080784

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

A thermodynamic argument is used to show that all colligative properties of a substance 2 (solute) in a solution with a liquid substance 1 (solvent) differ from those of the pure condensed phase of solute precisely as if the internal tension between molecules of solute in the solution was increased by π2, the osmotic pressure of solute in the solution. It follows from this argument that molecules of solvent serve both to couple the molecules of solute and to enhance the tension in the coupling force between them by an amount π2. It may be inferred that pressure dependent chemical properties, like all partial molar quantities of the solute, are altered by this enhanced internal tension. A plausible mechanism is proposed by which the internal solute and solvent tensions are enhanced, as required by thermodynamic argument.

 

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