The Gas Chromatography of Diene Tricarbonyl Iron Complexes
作者:
E.J. Forbes,
M.K. Sultan,
P.C. Uden,
期刊:
Analytical Letters
(Taylor Available online 1972)
卷期:
Volume 5,
issue 12
页码: 927-930
ISSN:0003-2719
年代: 1972
DOI:10.1080/00032717208062157
出版商: Taylor & Francis Group
关键词: Gas-liquid chromatography;organometallic compounds;diene tricarbonyl iron complexes;quantitation;thermal stability.
数据来源: Taylor
摘要:
Successful gas chromatographic elution of a range of diene tricar-bonyl from complexes has been achieved for the first time. Provided that precautions were taken to exclude air and prevent prolonged exposure to light many of those supposedly ‘unstable’ compounds could be gas chroma-tographed at temperatures up to 150[ddot] with no apparent thermal decomposition. Teflon columns employing E-301 methyl silicone gum as stationary phase gave best results, symmetrical gausssian peaks being obtained for most compounds with quantitative response to the microgram level.
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