Dielectric Constants of Some Miscible Aqueous-Organic Solvent Mixtures
作者:
B.R. Pujari,
B. Barik,
B. Behera,
期刊:
Physics and Chemistry of Liquids
(Taylor Available online 1998)
卷期:
Volume 36,
issue 2
页码: 105-112
ISSN:0031-9104
年代: 1998
DOI:10.1080/00319109808030599
出版商: Taylor & Francis Group
关键词: Dielectric constants;aqueous-organic solvent mixtures;hydration number;water structure
数据来源: Taylor
摘要:
The dielectric constants of some aqueous-organic solvent mixtures have been analysed by an equation analogous to Grunberg and Nissan equation. The hydration numbers are found out at the maxima and minima of the plots of Δϵ versusx2. The extent of hydration of organic solvents is discussed in the light of structure of the solvents. It is shown that the equations can be very well applied to aqueous-organic solvent mixtures. An interaction parameterdis defined to fit the dielectric constant data of the mixtures which bears a linear relationship with ϵ2.
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