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Phonon-assisted current in organic molecular crystals

 

作者: P. Gosar,   I. Vilfan,  

 

期刊: Molecular Physics  (Taylor Available online 1970)
卷期: Volume 18, issue 1  

页码: 49-61

 

ISSN:0026-8976

 

年代: 1970

 

DOI:10.1080/00268977000100051

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

It is shown that in organic molecular crystals the fluctuations of the intermolecular electron jump frequencies resulting from the lattice vibrations may produce a considerable increase of the total electric current. An expression for the current density operator, which takes into account the electron-phonon interactions, is derived and the corresponding linear response theory of the electrical conductivity is formulated. The phonon-assisted current can be partially accounted for by the proper corrections of the electron velocities used in a simple band theory calculation. These corrections are explicitly calculated for a three-dimensional parabolic and a one-dimensional narrow electron energy band.

 

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