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A Spectrophotometric Study of the Molybdenum(VI)-1-Pyrrolidinecarbodithioate System

 

作者: AlbertP. Lee,   D.F. Boltz,  

 

期刊: Analytical Letters  （Taylor Available online 1975）
卷期: Volume 8, issue 5  

页码: 345-358

 

ISSN:0003-2719

 

年代: 1975

 

DOI:10.1080/00032717508058216

 

出版商: Taylor & Francis Group

 

关键词: analysis;molybdenum;ammonium pyrrolidinecarbodithioate;spectrophotometry;extraction

 

数据来源: Taylor

 

摘要:

A spectrophotometric study of the molybdenum-1-pyrrolidinecarbodithioate complex has shown that the meta1:ligand ratio is 1;2. Both molybdenum(VI) and molybdenum(V) form complexes with almost identical absorption spectra. The conditional extraction constant for the molybdenum(VI)-1-pyrrolidinecarbodithioate in chloroform system has been evaluated as 6.3 × 1016.

 

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