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The Renner effect and spin-orbit coupling

 

作者: J.A. Pople,  

 

期刊: Molecular Physics  (Taylor Available online 1960)
卷期: Volume 3, issue 1  

页码: 16-22

 

ISSN:0026-8976

 

年代: 1960

 

DOI:10.1080/00268976000100021

 

出版商: Taylor & Francis Group

 

数据来源: Taylor

 

摘要:

The Renner theory of vibrational-electronic interaction in linear triatomic molecules in Π electronic states is extended to take account of coupling between an odd electron spin and the electron orbital angular momentum. Perturbation expressions for the splittings and shifts of energy levels are obtained on the assumption that the Renner splittings and the spin-orbit coupling energy are of the same order of magnitude, but less than the energy quantum of the bending vibrations.

 

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