Free-Radical Species from Methyl Vinyl Ketone in Aqueous Solution: A Pulse Radiolysis Study
作者:
Manmohan Kumar,
M.H. Rao,
P.N. Moorthy,
期刊:
Journal of Macromolecular Science: Part A - Chemistry
(Taylor Available online 1990)
卷期:
Volume 27,
issue 3
页码: 299-308
ISSN:0022-233X
年代: 1990
DOI:10.1080/00222339009349553
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Transient species (T1and T2), formed respectively by the reactions of hydrated electrons and hydroxyl radicals with methyl vinyl ketone monomer in aqueous solution, were characterized by their spectra, redox behavior, and decay kinetics. These were found to have λmaxat 290 and 310 nm with low extinction coefficient values of 94 and 70 m2/mol, respectively. Rate constants for the reactions of methyl vinyl ketone with eaaq- and OH were found to be 3.2 × 109 and 7 × 108 dm3·mol−1·s−1, respectively. the first propagation step for species T2 was found to be much faster (κpl∼ 1.5 × 106 dm3·s−1than that for species T1(κpl∼7.0 × 105 dm3·mol−1·s−1). Both were found to be reducing in nature, and the rate constants for the reduction of thionine and safranine with these species were determined. the most probable structures of these species are suggested.
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