THE ROLE OF HUMIC SUBSTANCES IN THE PHOTOCATALYTIC DEGRADATION OF WATER CONTAMINANTS
作者:
C. Minero,
E. Pelizzetti,
M. Sega,
S. E. Friberg,
J. Sjö blom,
期刊:
Journal of Dispersion Science and Technology
(Taylor Available online 1999)
卷期:
Volume 20,
issue 1-2
页码: 643-661
ISSN:0193-2691
年代: 1999
DOI:10.1080/01932699908943812
出版商: Taylor & Francis Group
数据来源: Taylor
摘要:
Photocatalysis over irradiated Ti02has been proved to efficiently abate more than 80% of the organic carbon pertaining to a commercial humic acid (HA). The presence of HA up to 50 mg L−1has been found to decrease the degradation rate of some model pollutants, namely phenol, 2,4-dichlorophenol and tetrachloromethane. However, the total organic carbon measurements and chloride evolution ensure that the disappearance of the initial pollutants is not due to binding to HA structure, but to an efficient mineralization process. HA' s are able to scavenge both the oxidative and the reductive active species as shown by the inhibiting effect on the rate of disappearance of phenol and 2,4-dichlorophenol (essentially oxidative), and of CCI4 (initially reductive).
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