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Theory of polymer crystal thickening during annealing

 

作者: I. C. Sanchez,   A. Peterlin,   R. K. Eby,   F. L. McCrackin,  

 

期刊: Journal of Applied Physics  (AIP Available online 1974)
卷期: Volume 45, issue 10  

页码: 4216-4219

 

ISSN:0021-8979

 

年代: 1974

 

DOI:10.1063/1.1663038

 

出版商: AIP

 

数据来源: AIP

 

摘要:

A previous theory of thickening has been extended to encompass the possible dependence of cooperative chain transport on lamella thickness and crystallinity changes during annealing. These have marked effects on the thickening rate leading to changes in slope and departures from straight‐line behavior of the plots of lamella thickness versus the logarithm of time. The resulting curves bear a resemblance to many exprimental ones in the literature. Also brought out by the analysis is the important fact that the volumes of the coherently thickening domains are not known from experiment.

 

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