Theory of polymer crystal thickening during annealing
作者:
I. C. Sanchez,
A. Peterlin,
R. K. Eby,
F. L. McCrackin,
期刊:
Journal of Applied Physics
(AIP Available online 1974)
卷期:
Volume 45,
issue 10
页码: 4216-4219
ISSN:0021-8979
年代: 1974
DOI:10.1063/1.1663038
出版商: AIP
数据来源: AIP
摘要:
A previous theory of thickening has been extended to encompass the possible dependence of cooperative chain transport on lamella thickness and crystallinity changes during annealing. These have marked effects on the thickening rate leading to changes in slope and departures from straight‐line behavior of the plots of lamella thickness versus the logarithm of time. The resulting curves bear a resemblance to many exprimental ones in the literature. Also brought out by the analysis is the important fact that the volumes of the coherently thickening domains are not known from experiment.
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