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Kinetics of reconstructive austenite to ferrite transformation in low alloy steels

 

作者: ReedR. C.,   BhadeshiaH. K. D. H.,  

 

期刊: Materials Science and Technology  (Taylor Available online 1992)
卷期: Volume 8, issue 5  

页码: 421-436

 

ISSN:0267-0836

 

年代: 1992

 

DOI:10.1179/mst.1992.8.5.421

 

出版商: Taylor&Francis

 

数据来源: Taylor

 

摘要:

AbstractA thermodynamic model has been coupled with simplified kinetic theory, so that, subject to a number of assumptions, the one-dimensional parabolic thickening constantα1for allotriomorphic ferrite growing from austenite can be estimated as a function of temperature and composition. To do this, kinetic theory for ternary Fe–C–X systems (where X represents a substantial alloying element) is extended to multicomponent alloys. Values ofα1calculated assuming local equilibrium and paraequilibrium are compared. Consistent with recent calculations, the slope of theα1versus temperature plot is found to change abruptly on entry into the negligible partitioning local equilibrium regime, consistent with an increase in interfacial velocity. At very high supersaturations, the effect of the cross-terms in the diffusivity matrix appears to be small and only then can their effect be ignored. At temperatures below the Ae3′, the value ofα1, calculated assuming local equilibrium, is less than that calculated assuming paraequilibrium. Classical nucleation theory is used to model the ferrite allotriomorphs as discs growing from prior austenite grain boundaries. It has been demonstrated that the model developed here can reproduce the C-curve behaviour typical of those parts of the time–temperature–transformation diagrams that are due to allotriomorphic ferrite, provided the paraequilibrium mode of transformation is assumed to be operative. This work therefore suggests that in multicomponent alloys, the state of true local equilibrium does not exist at the advancing interface. Some problems associated with the paraequilibrium mode of transformation during reconstructive growth are discussed.MST/1452

 

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