On the temperature dependence of the activation enthalpy for sucrose hydrolysis
作者:
J. Richard Ward,
期刊:
International Journal of Chemical Kinetics
(WILEY Available online 1985)
卷期:
Volume 17,
issue 1
页码: 11-15
ISSN:0538-8066
年代: 1985
DOI:10.1002/kin.550170103
出版商: John Wiley&Sons, Inc.
数据来源: WILEY
摘要:
AbstractRecent interest in the measurement and the interpretation of heat capacities of activation has led to more rigorous methods to detect temperature‐varient activation parameters. One such method devised by Blandamer and co‐workers was applied to the sucrose hydrolysis data of Moelwyn‐Hughes and Leininger and Kilpatrick. Both sets of investigators claimed that the energy of activation for sucrose inversion decreased with increasing temperature, while Heidt and Purvis and more recently, Kuhler's group contend that the energy of activation is constant. It was found that neither the data of Moelwyn‐Hughes nor of Leininger and Kilpatrick warrant the inclusion of a temperature‐dependent activation
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